Oxide superconductor having the formula Pba (M1-x-y Cex Sry)4 Cu3-a Oz where M is at least one rare earth element

ABSTRACT

An oxide superconductor which has a composition expressed by the following general formula and whose crystal structure is 1222-phase structure. 
     
         Pb.sub.a (M.sub.1-x-y Ce.sub.x Sr.sub.y).sub.4 Cu.sub.3-a O.sub.z (I) 
    
     (where M represents at least one element selected from the group consisting of Y, La, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, and Lu, and a, x, y, and z denote the numbers which satisfy 0.3≦a≦0.7, 0&lt;x≦0.25, 0.3≦y&lt;0.5, 8.5≦z≦9.5, respectively). A Pb-based Cu oxide superconductor manufacturing method comprising the steps of mixing powders of raw materials containing at least Pb, Sr, Ce, M (where M represents at least one element selected from the group consisting of Y, La, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, and Lu groups) and Cu in the proportion to have the composition shown in the general formula (I) above, optionally forming the mixed powder into a shape body, and firing the obtained powder mixture or the shape body in the temperature range of 900°-1150° C. in the oxidizing atmosphere.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to an oxide superconductor having a novel composition and its manufacturing method.

2. Description of the Related Art

As oxide superconductors containing Pb and Cu (hereinafter called "Pb-based Cu oxide superconductor"), Pb₂ Sr₂ (Ca,Y)Cu₃ O₈ with 2213 phase crystal structure (see R. J. Cava et al., Nature 336, pp 211, 1988), Pb₂ (Sr,La)₂ Cu₂ O₆ with 2202 phase structure (see H. W. Zandbergen et al., Physica C 159, pp 81, 1989), (Pb,Sr)Sr₂ (Y,Ca)Cu₂ O₇ (see T. Rouillon et al., Physica C 159, pp 201, 1989) or (Pb,Cu)(Sr,Ba)₂ (Y,Ca)Cu₂ O₇ (see S. Koriyama et al., Physica C 166, pp 413, 1990), both with 1212 phase structure, PbSrBa(Y,Ca)Cu₃ O₈ with 1213 phase structure (see A. Tokiwa et al., Physica C 161, pp 459, 1989), (Pb,Cu)(Sr,La)₂ CuO₅ with 1201 phase structure (see S. Adachi et al., Jpn. J Appl. Phys. 29 pp. l890, 1990) have been known.

Because in these superconductors, the oxygen content in its composition is nonstoichiometric (unable to be reduced to simple integer ratio), the numbers denoting oxygen content in the above-mentioned compositional formulae indicate the ideal value. In actuality, it is assumed that the oxygen content deviates slightly from the above numbers. Of the Pb-based Cu oxide superconductors of above-mentioned composition, those containing Y are known to exhibit superconductivity characteristics even if other rare earth elements are used in place of Y.

Now when superconducting materials are used in various sensors and devices, various characteristics are required according to respective applications. For example, they must have suitable critical temperatures, must be easy to be synthesized, must have the precise structure, or must be easy to handle.

Investigating the above-mentioned Pb-based Cu oxide superconductors in respect to these viewpoints, synthesis of say a 2213-phase structure, a 2202-phase structure, and a 1213-phase structure Pb-based Cu oxide superconductors is carried out by firing material powders, a mixture of oxides, carbonates and so on, in reducing atmospheres. During firing the material powders, pinpoint control of oxygen partial pressure in the atmosphere is essential and furthermore, rapid cooling is required after firing, and therefore, such Pb-based Cu oxide superconductors are not always synthesized easily. Of the 1212-phase structures, those comprising (Pb₀.5 Sr₀.5) Sr₂ (Y,Ca)Cu₂ O₇ must have their synthesis carried out in the vacuum atmosphere.

In this way, Pb-based Cu oxide superconductors of 2213 phase, 2202 phase, 1213 phase, and 1212 phase structures with the aforementioned composition are not always easy to be synthesized. Furthermore, synthesis of Pb-based Cu oxide superconductors with the above-mentioned structures is carried out in either a reducing or a vacuum atmosphere as described above. In general, the melting point of oxides lowered in such atmosphere. Consequently, the firing temperature must be lower than that in oxidizing atmospheres, resulting in a problem that Pb-based Cu oxide superconductors obtained are difficult to be densified.

Of Pb-based Cu oxide superconductors of the 1201-phase structure and the 1212-phase structure, those comprising (Pb,Cu)(Sr,Ba)₂ (Y,Ca)Cu₂ O₇ can be synthesized in an oxidizing atmosphere and the problem as mentioned above would not occur. However, Pb-based Cu oxide superconductors of this composition contain a high content of Pb, a harmful element, requiring careful handling. This constitutes a disadvantage to produce practical Pb-based Cu oxide superconductors.

SUMMARY OF THE INVENTION

The object of this invention is to provide a new Pb-based Cu oxide superconductor and its manufacturing method, which can solve the above-mentioned problems related to Pb-based Cu oxide superconductors, which does not need special controls for the baking temperature and any rapid cooling process, which can be easily and finely synthesized in the suitable oxidizing atmosphere, and which contains only a small amount of Pb.

The 1222-phase structure contains a structure unit known as a fluorite layer. And of copper oxides containing this fluorite layer, those such as (Nd,Ce)₂ (Nd,Ba)₂ Cu₃ O₉, which exhibits superconductivity, exist (see H. Sawa et al., J. Phys. Soc. Japan, 58, pp 2252, 1989).

The inventors of the present invention had considered the fact that many of the Cu oxide superconductors containing this fluorite layer contain Ce and can be synthesized to Pb-based Cu oxide superconductors in the oxidizing atmosphere, similar to (Pb,Cu)(Sr,Ba)₂ (Y,Ca)Cu₂ O₇, and that the Pb-based Cu oxide superconductors of a 1222-phase structure is expected to contain less Pb than the aforementioned conventional Pb-based Cu oxide superconductors with a 1212-phase structure, and have succeeded in developing the Pb-based Cu oxide superconductor of the present invention.

That is, the present invention provides oxide superconductors having the composition expressed by the following formula: Pb_(a) (M_(1-x-y) Ce_(x) Sr_(y))₄ Cu_(3-a) O_(z) (where M represents at least one element selected from the group consisting of Y, La, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, and Lu, and a, x, y, and z denote the numbers which satisfy 0.3≦a≦0.7, 0<x≦0.25, 0.3 ≦y<0.5, 8.5 ≦z≦9.5, respectively) and the crystal structure is of the 1222 phase structure. The present invention provides a Pb-based Cu oxide superconductor manufacturing method comprising the steps of mixing powders of raw materials containing at least Pb, Sr, Ce, M (where M represents at least one element selected from the group consisting of Y, La, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, and Lu) and Cu in the proportion to have the above-mentioned composition, optionally forming the mixed powder of raw materials into a shape body and firing the obtained powder mixture or the shape body in the temperature range of 900°-1150° C. in the oxidizing atmosphere.

The oxide superconductors of the present invention are Pb-based Cu oxide superconductors which possess the above-mentioned composition and whose crystal structure is of the 1222-phase.

Additional objects and advantages of the invention will be set forth in the description which follows, and in part will be obvious from the description, or may be learned by the practice of the invention. The objects and advantages of the invention may be realized and obtained by means of the instrumentalities and combinations particularly pointed out in the appended claims.

BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings, illustrate presently preferred embodiments of the invention, and together with the general description given above and the detailed description of the preferred embodiments given below, serve to explain the principles of the invention.

FIG. 1 is a schematic diagram showing a crystal structure of Pb-based Cu oxide superconductors of the present invention.

FIG. 2 is a graph showing the temperature dependency of electric resistivity in Embodiment (Example) 1.

FIG. 3 is a graph showing the temperature dependency of d.c. magnetic susceptibility in Embodiment (Example) 1.

FIG. 4 is a graph showing an X-ray diffraction pattern in Embodiment 1.

FIG. 5 is a graph showing the temperature dependency of electric resistivity in Embodiment (Example) 32.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

FIG. 1 shows an example of the crystal structure of Pb-based Cu oxide superconductor of the present invention when M in the above composition is Eu.

The crystal structure of this case is a tetragonal crystal of the lattice constant a of about 3.8 Å and c of about 29 Å which is known as a material of T1Ba₂ (M,Ce)₂ Cu₂ O₈ (where M is the same as above) and Pb-Pr-Sr-Cu-O systems (for the T1 system, see S. Martin et al., Mcd. Phys. Lett. B3, pp 993, 1989 and for the Pb system, see S. Adachi et al., Physica C 168, pp 1, 1990). However, these are not superconducting materials.

In Pb-based Cu oxide superconductors of the present invention, because when the character a is smaller than 0.3 or larger than 0.7, impurity phases such as the 1212 phase are generated in the crystal structure in addition to the 1222 phase and this generation degrades superconducting characteristics, the value a must be restricted to the range of 0.3-0.7.

Character x indicating the Ce content is also restricted to the range of 0<x≦0.25. Deviating from this range, will result that Pb-based Cu oxide superconductors of the 1222-phase structure cannot be obtained.

Character y indicating the Sr content is also restricted to the range of 0.3≦y<0.5. Deviating from this range will result that Pb-based Cu oxide superconductors of the 1222-phase structure cannot be obtained as with the case of character x.

The oxygen content z varies according to firing conditions and cooling conditions later discussed, but must be the amount that allows the obtained synthesized substance to be an oxide superconductor. Specifically, it is restricted to the range of 8.5≦z≦9.5. This is because deviation of z from this range degrades the superconducting properties.

The Pb-based Cu oxide superconductor of the present invention can be synthesized as follows. First, powders of raw materials containing Pb, Ce, Sr, Cu, and M are thoroughly mixed. Examples for raw materials used in this event include o ides containing the elements described above, carbonate, nitrate, oxalate, hydroxide, etc.

The mixture ratio of each materials is decided in such a way that the above-mentioned metallic elements contained in the materials constitute the composition of Pb_(a) (M_(1-x-y) Ce_(x) Sr_(y))₄ Cu_(3-a) after synthesis.

According to the present invention, the obtained powder mixture of raw material is calcined at 800° to 900° C. in an oxidizing atmosphere. After the calcined powder is formed into the desired shape by a molding method such as a press molding, an injection molding, an extrusion molding and a sheet molding, the shape body is fired.

Then, the obtained calcined powder or the shape body is fired in the oxidizing atmosphere. In an oxidizing atmosphere, the oxygen partial pressure need not specially be controlled as required conventionally and the applied atmosphere may be, say, ambient air or a 100% oxygen gas atmosphere.

The baking temperature is set to the temperature range from 900°-1150° C. When the firing temperature is lower than 900° C., 1222-phase structure generating reactions do not take place satisfactorily and synthesis of Pb-based Cu oxide superconductors of the above-mentioned composition and fine structure does not progress. When the firing temperature is higher than 1150° C., evaporation of Pb proceeds and impurity phases other than the 1222 phase structure begin to form accordingly.

In the temperature range mentioned above, reactions to generate the Pb-based 1222-phase structure take place while undergoing a partial melting state. For this reason, firing at the above-mentioned temperature range causes the reactions to generate the Pb-based 1222-phase structure to take place rapidly, and as a result, Pb-based Cu oxide superconductors with a 1222-phase structure of the present invention are synthesized in extremely short time. Preferable baking temperatures are 1000°-1080° C.

Excessively long firing times accelerates evaporation of Pb, resulting in deterioration of superconducting characteristics due to generation of impurity phases. Excessively short firing times result in insufficient generation of the 1222-phase structure, which proceeds in the partial melting state. It is, therefore, desirable to set the firing time to the range of 0.5-5 hours at the above-mentioned temperatures.

Upon completion of firing, the synthesized substance is cooled to obtain Pb-based Cu oxide superconductors of the present invention.

The desirable cooling rate at this event is 10° C./min or over up to the temperature right below the partial melting temperature (about 900° C.). Slower cooling rates than this increases the Pb evaporation rate. From the temperature right below the partial melting temperature to about 300° C., the cooling rate of 5° C./min or lower is desirable. A cooling rate higher than this results in insufficient take-in of oxygen during cooling, which is essential for occurrence of superconducting characteristics.

EXAMPLES 1-11, COMPARISON EXAMPLE 1-11

Powders of PbO, CeO₂, Eu₂ O₃, SrCO₃, and CuO (purity: all 99.9% or higher) were thoroughly mixed to have the composition shown in Table 1.

Each powder mixture obtained is calcined for 10 hours in the 850° C. air to form into compacts having desired shape. The compacts were fired under the conditions mentioned in Table 1 and finally the fired compacts were cooled at a rate of 1° C./min.

For each sample obtained, the generated phase was confirmed by the X-ray diffraction method and electric resistivity was measured by the four-probe method to investigate superconducting characteristics.

Table 1 summarizes the above results.

For the superconductor compacts of Embodiment 1, temperature dependency of electric resistivity and d.c. magnetic susceptibility were investigated and the results are shown in FIGS. 2 and 3. As clear from FIG. 2, the oxide superconductor of the present invention begins decreasing electric resistivity from 25K and attains zero at 12K by superconducting transition. As clear from FIG. 3, magnetic susceptibility becomes negative at 25K or lower for the Meissner effect due to superconductivity.

FIG. 4 shows an X-ray (CuKc) diffraction pattern of the oxide superconductor of Embodiment 1. As clear from FIG. 4, this oxide superconductor is a tetragonal crystal with the lattice constant a of about 3.8 Å and c of about 29.6 Å, and all the diffraction peaks can be characterized. It forms, as a whole, a single phase of 1222 phase structure.

EXAMPLES 12-28

As shown in Table 2, various oxide superconductors were synthesized in the manner similar to Embodiment 1 except a change of the type of element M. All oxide superconductors obtained were extremely densified. Table 2 shows the generated phases and superconducting characteristics together.

EXAMPLES 29-31

The powder mixture same as that of Embodiment 1 was fired under the same conditions and the fired compacts obtained were cooled to 850° C., 800° C., and 700° C., respectively, in 10 minutes, then cooled to room temperature at a rate of 1° C./min and three types of oxide superconductor compacts of varying cooling conditions were fabricated.

These three types of oxide superconductor compacts all had the 1222-phase crystal structure and the Tc (onset) is all 28K, exhibiting characteristics superior to oxide superconductors of Embodiment 1.

EXAMPLE 32

Oxide superconductor compacts of Embodiment 1 were held at 800° C. for 1 hour in the 1 atm. oxidizing atmosphere and cooled to room temperature at a rate of 1° C./min. In the cooling process, oxide superconductor compacts were held at 600° C., 500° C., 400° C., and 300° C. for 10 hours, respectively.

Temperature dependency of electric resistivity was measured on heat-treated superconductor compacts obtained, and the results are shown in FIG. 5.

As shown in FIG. 5, lowering of electric resistivity due to superconducting transition was recognized at 30K or lower, and the characteristics are improved from those of Embodiment 1.

According to the X-ray diffraction, the crystal structure of the heat treated superconductor compacts is the 1222-phase structure and change of crystal structure due to heat treatment was not recognized.

As is clear from the above description, the oxide superconductor of the present invention is a new Pb-based Cu oxide superconductor with the 1222-phase structure, which has superconducting transition temperature of 20-30K and whose structure is extremely densified, and is very easy to handle because the Pb content is low. Because this oxide superconductor contains Pb, it provides excellent workability as compared to other oxide superconductors and can be used for new material for sensors and devices.

With the manufacturing method of the present invention, synthesis is carried out in the oxidizing atmosphere and firing temperature can be increased, and as a result, oxide superconductors with high density structure can be synthesized easily and at low cost.

Additional advantages and modifications will readily occur to those skilled in the art. Therefore, the invention in its broader aspects is not limited to the specific details, representative devices, and illustrated examples shown and described herein. Accordingly, various modifications may be made without departing from the spirit or scope of the general inventive concept as defined by the appended claims and their equivalents.

                                      TABLE 1                                      __________________________________________________________________________                    Baking condition   Superconducting                                             Baking  Oxygen     characteristics                              Pb.sub.a (Eu.sub.1-x-y Ce.sub.x Sr.sub.y).sub.4                                               temp-                                                                              Baking                                                                             partial       Tc  Tc (zero                              Cu.sub.3-a O.sub.9                                                                            erature                                                                            time                                                                               pressure                                                                            Generated                                                                            Yes/                                                                              (onset,                                                                            resist-                               a      x   y   (°C.)                                                                       (hr)                                                                               (atm)                                                                               Phase No K)  ance, K)                                                                            Remarks                          __________________________________________________________________________     Embodi-                                                                             0.5                                                                              0.125                                                                              0.4375                                                                             1080                                                                               1   1.0  1222  Y  25  12                                    ment 1                      phase                                              Embodi-                                                                             0.5                                                                              0.125                                                                              0.4375                                                                             1080                                                                               1   0.2  1222  Y  20  11                                    ment 2                      phase                                              Embodi-                                                                             0.5                                                                              0.125                                                                              0.4375                                                                             1000                                                                               1   1.0  1222  Y  22  10                                    ment 3                      phase                                              Embodi-                                                                             0.5                                                                              0.125                                                                              0.3 1080                                                                               1   1.0  1222  Y  18   6                                    ment 4                      phase +                                                                        impurity                                                                       phase                                              Embodi-                                                                             0.5                                                                              0.1 0.4375                                                                             1080                                                                               1   1.0  1222  Y  20  10                                    ment 5                      phase                                              Embodi-                                                                             0.5                                                                              0.125                                                                              0.4375                                                                             1080                                                                               1   1.0  1222  Y  15   5                                    ment 6                      phase +                                                                        impurity                                                                       phase                                              Embodi-                                                                             0.3                                                                              0.125                                                                              0.4375                                                                             1080                                                                               1   1.0  1222  Y  13  --                                    ment 7                      phase +                                                                        impurity                                                                       phase                                              Embodi-                                                                             0.7                                                                              0.125                                                                              0.4375                                                                             1080                                                                               1   1.0  1222  Y  10  --                                    ment 8                      phase +                                                                        impurity                                                                       phase                                              Embodi-                                                                             0.5                                                                              0.125                                                                              0.375                                                                              1080                                                                               1   1.0  1222  Y  20  11                                    ment 9                      phase                                              Embodi-                                                                             0.5                                                                              0.125                                                                              5/12                                                                               1080                                                                               1   1.0  1222  Y  25  10                                    ment 10                     phase                                              Embodi-                                                                             0.5                                                                              0.1 0.45                                                                               1080                                                                               1   1.0  1222  Y  19   9                                    ment 11                     phase                                              Compar-                                                                             0.5                                                                              0.125                                                                              0.4375                                                                             1150                                                                               1   1.0  1222  N  --  --   Slight-                          ison 1                      phase +           ly                                                           impurity          melted                                                       phase                                              Compar-                                                                             0.5                                                                              0.125                                                                              0.4375                                                                              900                                                                               1   1.0  1222  N  --  --                                    ison 2                      phase +                                                                        impurity                                                                       phase                                              Compar-                                                                             0.5                                                                              0.125                                                                              0.4375                                                                             1080                                                                               1    0.05                                                                               1222  N  --  --                                    ison 3                      phase                                              Compar-                                                                             0.5                                                                              0.125                                                                              0.5 1080                                                                               1   1.0  Impurity                                                                             N  --  --                                    ison 4                      phase                                              Compar-                                                                             0.5                                                                              0.125                                                                              0.25                                                                               1080                                                                               1   1.0  1222  N  --  --                                    ison 5                      phase +                                                                        impurity                                                                       phase                                              Compar-                                                                             0.5                                                                              --  0.4375                                                                             1080                                                                               1   1.0  Impurity                                                                             N  --  --                                    ison 6                      phase                                              Compar-                                                                             0.5                                                                              0.3 0.4375                                                                             1080                                                                               1   1.0  1222  N  --  --                                    ison 7                      phase +                                                                        impurity                                                                       phase                                              Compar-                                                                             0.2                                                                              0.125                                                                              0.4375                                                                             1080                                                                               1   1.0  Impurity                                                                             N  --  --                                    ison 8                      phase                                              Compar-                                                                             0.8                                                                              0.125                                                                              0.4375                                                                             1080                                                                               1   1.0  Impurity                                                                             N  --  --                                    ison 9                      phase                                              Compar-                                                                             0.5                                                                              0.125                                                                              0.4375                                                                             1080                                                                               6   1.0  1222  Y  15   6                                    ison                        phase +                                            10                          impurity                                                                       phase                                              Compar-                                                                             0.5                                                                              0.125                                                                              0.4375                                                                             1080                                                                               5   1.0  1222  Y  23   8                                    ison                        phase                                              11                                                                             __________________________________________________________________________

                                      TABLE 2                                      __________________________________________________________________________             Type of element  Superconducting characteristics                               M in the Generated           Tc (zero                                          composition                                                                             phase   Yes/No                                                                              Tc (onset, K)                                                                         resistance, K)                            __________________________________________________________________________     Embodiment 12                                                                          Y        1222 phase                                                                             Y    20     11                                        Embodiment 13                                                                          La       1222 phase +                                                                           Y    10     --                                                         impurity phase                                                Embodiment 14                                                                          Nd       1222 phase +                                                                           Y    12     --                                                         impurity phase                                                Embodiment 15                                                                          Sm       1222 phase                                                                             Y    19     6                                         Embodiment 16                                                                          Gd       1222 phase                                                                             Y    21     10                                        Embodiment 17                                                                          Tb       1222 phase                                                                             Y    21     9                                         Embodiment 18                                                                          Dy       1222 phase                                                                             Y    20     9                                         Embodiment 19                                                                          Ho       1222 phase                                                                             Y    20     9                                         Embodiment 20                                                                          Er       1222 phase                                                                             Y    19     8                                         Embodiment 21                                                                          Yb       1222 phase                                                                             Y    18     8                                         Embodiment 22                                                                          Lu       1222 phase                                                                             Y    16     6                                         Embodiment 23                                                                          Eu + Ho  1222 phase                                                                             Y    22     13                                        Embodiment 24                                                                          Ho + Y   1222 phase                                                                             Y    20     12                                        Embodiment 25                                                                          Sm + Lu  1222 phase                                                                             Y    19     11                                        Embodiment 26                                                                          Eu + Nd  1222 phase +                                                                           Y    11     --                                                         impurity phase                                                Embodiment 27                                                                          Er + Nd  1222 phase +                                                                           Y     8     --                                                         impurity phase                                                Embodiment 28                                                                          Eu + Y + Ho                                                                             1222 phase                                                                             Y    17     9                                         __________________________________________________________________________ 

What is claimed is:
 1. An oxide superconductor comprising a composition expressed by the following formula (I) and whose crystal structure is a 1222-phase structure:

    Pb.sub.a (M.sub.1-x-y Ce.sub.x Sr.sub.y).sub.4 Cu.sub.3-a O.sub.z (I)

where M represents at least one element selected from the group consisting of Y, La, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb and Lu, and a, x, y, and z denote numerals which satisfy the following relationships: 0.3≦a≦0.7, 0<x≦0.25, 0.3≦y<0.5 and 8.5≦z≦9.5.
 2. The oxide superconductor according to claim 1, wherein a is 0.5.
 3. The oxide superconductor according to claim 1, wherein M is at least one rare earth element selected from the group consisting of Sm, Eu and Gd.
 4. The oxide superconductor according to claim 1, wherein M is a combination of Eu and Nd.
 5. The oxide superconductor according to claim 1, wherein M is Eu.
 6. The oxide superconductor according to claim 2, wherein M is at least one rare earth element selected from the group consisting of Sm, Eu and Gd.
 7. The oxide superconductor according to claim 2, wherein M is a combination of Eu and Nd.
 8. The oxide superconductor according to claim 2, wherein M is Eu.
 9. The oxide superconductor according to claim 8, wherein X is 0.125 and y is 0.4375.
 10. The oxide superconductor according to claim 8, wherein X is 0.125 and y is 0.3.
 11. The oxide superconductor according to claim 8, wherein X is 0.1 and y is 0.4375. 